Pickling

Pickling Silver

This term relates to the removal of firescale from silver by use of chemicals, often slightly warmed.

When heated, silver blackens on the surface. It is common in silversmithing to pickle the object, bringing the shine back.

There are several methods.

Hydrochloric acid is the most common chemical used. It normally is used in concentrations of 10% or less and often is slightly warmed in a soup warmer or other similar temperature controlled container

Hydrogen peroxide (sparex) solutions can be used, but are a bit slower. This also is used in a soup warmer.

Acetic acid, available from most chemists and home-brew suppliers, can be used but is so much slower that significantly long soaks are required.

The best solution for this is a 5% solution of citric acid or similar concentration of tri-sodium citrate.  This latter is best for glass, as it chelates the corrosion or stuck kiln wash, but does not etch the glass even after 48 hours soaking.

Revised 6.1.2022