Heavy Metals in Glass

Some concern has been expressed about the metals used in colouring glass.  This centres around the temperatures used in fusing and whether kiln workers may be of risk from these heavy metals vaporising.

First of all, let’s get some sense of perspective. This is from Greg Rawles, an acknowledged expert on the hazards of working with glass.

Understanding Exposure:

In reality, unless you are doing:
High-volume production work that exposes you to a health hazard all day long
You are exposing yourself to high levels of a health hazard for a brief time
You are working with a very toxic material
You are not working responsibly

You are not really at risk for an unacceptable exposure when working in a glass studio  http://www.gregorieglass.com/chemicals.html

Now, let’s think about how likely it is to have heavy metals vaporise at kiln forming temperatures. How stable would glass be if the metals that colour it vaporised when we fired it? the colour would vary with the heat and number of times we fired it.

Now, let’s think about how likely it is to have heavy metals vaporise at kiln forming temperatures. How stable would glass be if the metals that colour it vaporised when we fired it? the colour would vary with the heat and number of times we fired it.

Even if the metal were to evaporate, how much is in the glass. Apparently, Bullseye uses less than 3 pounds of cadmium for a pot of glass. We can tell from the sheet numbers that a pot of glass gives at least 2000 sheets of glass, so there is ca. 0.0015 lbs or .07 grams or less of metal in a sheet of 3mm glass. There is very little there to "vaporise", so even it were able to evaporate, it is in such small quantities as to be negligible, and the exposure so low as to be of extremely low risk. There is however, no risk in protecting yourself with dust masks. Just remember that the risks from vaporised heavy metals is much less than most of the other studio practices involving glass. If you need breathing protection for metals (and you may feel it is not worth the risk) then you need to be wearing a mask all the while you are doing glass work. It is about relative risk.

For complete information, the melting and boiling points of various metals relevant to glass colouring are given below.  The vaporisation will be somewhere above the melting point and toward the boiling point.  You will be able to see the relevant temperatures and take any precautions you feel are necessary.  Remember that the metals are not used in their pure forms, but as oxides.  These may have different melting and boiling temperatures.  In general, the oxides used in colouring glass have higher melting and boiling points than the pure metal.

Antimony -for whites

Melting point: 630C

Boiling point:  1635C

Antimony Oxide

Melting point:  380-930C

Boiling point:  1425C

Cadmium 

Melting point: 321C

Boiling point:  767C

Cadmium sulphide - yellow

Melting point: 1650-1830C

Boiling point:  2838C

Chromium 

Melting point: 1907C

Boiling point:  2671C

Chromic Oxide – for emerald green

Melting point: 4415C

Boiling point:  7230C

Cobalt 

Melting point: 1495C

Boiling point:  2927C

Cobalt Oxide- blue to violet

Melting point: 1900C

Copper 

Melting point: 1084C

Boiling point:  2562

Copper Oxides - for blue, green, red

Melting point: 1232-1326C

Boiling point:  1800-2000C

Gold

Melting point: 1337C

Boiling point:  2970C

Gold Chloride - red

Melting point: 170-254C

Boiling point:  298C

Iron

Melting point: 1538C

Boiling point:  2862C

Iron Oxide – for greens and brown

Melting point: 1377-1539C

Boiling point:  3414C

Lead – for yellows

Melting point: 327C

Boiling point:  1749C

Manganese 

Melting point: 1246C

Boiling point:  2061C

Manganese Dioxide – purple and a clarifying agent

Melting point: 535-888C

Neodymium

Melting point: 1024C

Boiling point:  3074C

Nickel 

Melting point: 1455C

Boiling point:  2730C

Nickel Oxide – for violet

Melting point (II - for green): 1955C

Melting point (III - for black): 600C

Selenium

Melting point: 221C

Boiling point:  685C

Selenium Oxide – for reds

Melting point: 118-340C

Boiling point:  350C

Silver 

Melting point: 961C

Boiling point:  2162C

Sodium

Melting point:  370C

Boiling point:   882C

Sodium Nitrate – a clarifying agent

Melting point: 308C

Boiling point:  380C

Sulphur

Melting point: 115C

Boiling point:  444C

Sulphur oxide - for yellow to amber

Melting point:  17C

Boiling point:   45C

Tin 

Melting point: 231C

Boiling point:  2602C

Tin Oxides – for whites

Melting point:  1080-1630C

Boiling point:  1800-1900C

Uranium

Melting point: 1132C

Boiling point:  4131C

Uranium oxide – for fluorescent yellow, green

Melting point:  1150-2765C

Boiling point:  1300C